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Clarifying study Defining Problems with Lithium-Air may still lead to Better Batteries

An MIT research team has studied in detail a promising next generation lithium battery know as a lithium-air or lithium- oxygen battery. This type of battery, which has the potential to offer more power by weight than the current lithium ion batteries, has had conflicting…

Rachel Kowalski
Rachel KowalskiCybersecurity Analyst
2 min read
Clarifying study Defining Problems with Lithium-Air may still lead to Better Batteries

An MIT research team has studied in detail a promising next generation lithium battery know as a lithium-air or lithium- oxygen battery. This type of battery, which has the potential to offer more power by weight than the current lithium ion batteries, has had conflicting and contradictory results in other studies, slowing down advancements to its development.

Iodide ions can make water more reactive, altering the reaction pathway during the discharge process.
Courtesy of the researchers

The MIT study, published in Energy and Environmental Science, focuses closely on lithium iodide, or LiI, a substance thought to aid or stabilize the reactions in the lithium-air batteries, in order to clarify and pinpoint the mechanism responsible for the batteries’ inconsistent results.

The lithium-oxygen battery is unique because one of the electrodes is made of air, instead of a heavyweight metal, while the other is composed of lithium, one of the lightest metals. This makes for an extremely lightweight battery, which if successful would be a huge advantage to the automotive field, making it possible to power a wider range of electric vehicles.

However, lithium-air batteries have a number of drawbacks, including a low number of total charge-recharge cycles, inefficient energy returns, and the high voltage charge requirements, caused by the unreliability of the oxygen electrode.

A number of scientists have suggested the use of LiI to resolve the problems but this substance has returned just as inconsistent results. The MIT team studied LiI both inside the battery itself and separately outside of the device.

Using a number of techniques, researchers found that the reaction of LiI and water produced lithium hydroxide which interfered with the batteries’ ability to charge. While this seems like a setback for LiI specifically and lithium-air batteries, in general, it may in fact still lead to lighter, better batteries.

Now that MIT researchers have identified the problems with LiI, further studies can work on finding other substances or solutions to the problems and still keep the potential of the lithium-air battery alive.

Lithium oxygen battery cell components were used for experiments in the lab. Photo: Karl-Lydie Jean-Baptiste/MIT

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Rachel Kowalski

Rachel Kowalski

Cybersecurity Analyst

Rachel Kowalski is the Cybersecurity Analyst at TrendinTech, where she covers vulnerabilities, ransomware, supply chain attacks, nation-state operations and the security rules shaping organizations in the United States and Europe. Before moving into journalism she worked as a threat intelligence analyst at a security vendor and later reported for CyberScoop and the security desk at Wired, covering the SolarWinds compromise and the ransomware wave that hit hospitals and pipelines. Rachel holds a Master of Science in Cybersecurity from the Georgia Institute of Technology and attends Black Hat and DEF CON in Las Vegas each year, where she follows research from the security community. She writes to make risks and countermeasures understandable to people who are not specialists.

All stories by Rachel Kowalski (214)