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Adding Fluorine Atoms to The Solar Cells Could Help To Improve Its Performance

Solar energy gets a boost this week as RIKEN researchers have now discovered that adding fluorine atoms to light harvesting polymers improves their efficiency. This is a breakthrough for companies manufacturing photovoltaic cells and products as performance in flexible solar cells can now be enhanced even more.

Owen Castellanos
Owen CastellanosHardware & Gaming Reporter
2 min read
Adding Fluorine Atoms to The Solar Cells Could Help To Improve Its Performance

Solar energy gets a boost this week as RIKEN researchers have now discovered that adding fluorine atoms to light harvesting polymers improves their efficiency. This is a breakthrough for companies manufacturing photovoltaic cells and products as performance in flexible solar cells can now be enhanced even more.

Typically, a polymer solar cell absorbs light through the use of a semiconducting polymer, which changes the electrons within the molecules from ground state to an excited state.  The chosen material then directs the electrons to an electrode where an electrical current is generated. These semiconducting polymers are great because they are lightweight and flexible as well as being semi-transparent. For this reason, they would be perfect for use in low-cost PV panels.  But currently, even the best polymer solar cells only convert around 10 percent of light, which is pretty weak.
Figure 1: By adding fluorine atoms to a light-absorbing polymer, RIKEN researchers have improved the efficiency of this photovoltaic cell. © 2016 Itaru Osaka, RIKEN Center for Emergent Matter Science

However, Itaru Osaka and colleagues at the RIKEN Center for Emergent Matter Science have now demonstrated that fluorine atoms offer potential improvements in this area.  They formed two polymers: PNTz4TF2 and PNTz4TF4. From their research, they found that adding fluorine lowered the energy level in the polymer which resulted in higher output voltage and less energy loss throughout the system. In particular, in the PNTz4TF2 the polymer strands were more rigid which allowed a faster movement of electrical charge flowing through.

Each polymer was then mixed with an electron acceptor (PC71BM) to see how it would react. With the PNTz4TF2 the team managed to achieve an efficiency of around 10.5 percent, which is only slightly better than a fluorine-free polymer, but an increase nonetheless.  The researchers are also feeling confident this can be improved further with a little more time and research and we may even see efficiency reach to as high as 15 percent.


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Owen Castellanos

Owen Castellanos

Hardware & Gaming Reporter

Owen Castellanos is the Hardware & Gaming Reporter at TrendinTech, where he tests graphics cards, processors, consoles and peripherals and follows the games industry, from the major publishers to independent studios. He previously wrote reviews and benchmarks for Tom's Hardware and contributed features to PC Gamer, covering everything from laptop testing to the economics of game development. Owen holds a Bachelor of Science in Electrical Engineering from the University of Texas at Austin and attends CES in Las Vegas, Computex in Taipei and the Game Developers Conference in San Francisco each year to meet chipmakers and developers. He writes for readers who want to know whether a product is worth the money, and he is not shy about saying when it is not.

All stories by Owen Castellanos (252)